Chapter 12 - Structure Determination: Mass Spectrometry And Infrared Spectroscopy Page 38

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Amines
Primary Amine (1°): Primary aliphatic amines display two well-defined peaks due to
asymmetric (higher frequency) and symmetric N-H stretching, separated by 80 to 100
-1
-1
cm
. Strong in-plane NH
scissoring absorptions at 1550 to 1650 cm
, and out-of-plane
2
-1
wagging at 650 to 900 cm
(usually broad) are characteristic of 1°-amines.
38

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