Periodic Table Long Form Page 4

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several
two and three-
The periodic table has
the conventional table. As long
dimensional periodic
as the medium-long-form prevailed
had some interesting
that subsequent
systems have been
it appeared as though lanthanum
redesigns including as a
atoms resume the
devised in order to
wheel or as these conical
and actinium were equally good
filling of s and p orbitals.
accommodate the transition
candidates for membership to
structures from 1947
And just as Mendeleev solved the
metals in novel ways
group three as were lutetium and
problem by removing his transition
(see above).
lawrencium. But with the growing
elements from the main body of
But there is still nothing drastic
willingness to display the elements in
the table, so modern chemists and
involved in these arrangements,
a long-form table, the choice in favour
physicists solved their problem by
despite their appearance. Tables
of lutetium and lawrencium becomes
removing a block of elements: the
with more significant variations
inescapable. If one places lanthanum
d block. But instead of placing these
place some elements in
and actinium below scandium and
new transition elements to the right
different groups. One such
yttrium in a long-form arrangement
of the main body of the table, they
radical arrangement is the
the sequence of atomic numbers
are traditionally placed between two
left-step periodic table in
is violated in a rather shocking
unevenly separated portions of the
which helium is placed at
manner.
main table, the s block and the p block.
the top of the alkaline earth
Finally, it appears that the
In the 1940s, American chemist
metals rather than at the top
recent synthesis of super-heavy
Glen Seaborg made a further
of the noble gases.
elements up to and including
modification to the periodic table, this
I suggest a table which
element 118, (with the exception
time involving the inner transition
would place hydrogen
of element 117), is reawakening an
elements called the actinides. As a
among the halogens, resulting
interest in how best to represent the
result of his work these elements
in a new perfect atomic number
periodic system.
– which had previously been housed
triad involving hydrogen, fluorine
With the possibly imminent advent
in the main body of the medium-
and chlorine (see below). Triads
of the g-block, formally starting at
long-form table – were also removed
were historically the first hint of
element 121, it will become necessary
to join the lanthanides and to create
a numerical regularity among the
to create a new block in the table.
the long-form periodic table
elements and many people have
Should this be placed as a footnote
(see page 48).
suggested placing hydrogen among
to a long-form table or perhaps
All these forms are still fairly
the halogens on the basis of chemical
incorporated into a very-long-form
traditional, although the act of
and physical evidence.
table with 50 columns? Needless to
One suggestion for a
removing elements from the main
An interesting debate has
say, several versions of both kinds can
reformed table is to
tables does not have to be carried out
developed over which elements
already be found – this is an issue that
place hydrogen with the
on a two-dimensional display. Today,
should be placed in group three of
halogens
won’t be resolved in a hurry.
Eric Scerri teaches chemistry and
history and philosophy of science at
UCLA in Los Angeles, US. He is the
author of The periodic table, its story
and its significance, Oxford University
Press, 2007
References
E R Scerri, Educ. Chem., 2005, 42, 135
E R Scerri, J. Chem. Educ., 2008, 85, 585
W B Jensen, J. Chem. Educ., 1982, 59, 634
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Chemistry World
March 2009
49

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