4
ST/SP/20152016/IPOY
42. Among the following, the molecule with highest dipole
48. A fuel has the same knocking property as a mixture of 70%
moment is
isooctane (2, 2, 4trimethyl pentane) and 30% nheptane
by volume. The octane number of the fuel is
(1) CH
Cl
(2) CH
Cl
3
2
2
(1) 100
(2) 70
(3) CHCl
(4) CCl
3
4
(3) 30
(4) 40
43. Which of the following is correct order of electronegativity
of Xe in the given compounds?
49. The product of the following reaction
(1) XeF
< XeF
< XeO
F
< XeO
6
4
2
2
3
CH
3
|
(2) XeO
< XeO
F
< XeF
< XeF
g
3
2
2
4
6
(i)Hg(OAC) H O
¾¾¾¾¾¾¾ ®
is
CH
-
CH
- =
C CH
2
2
3
2
2
-
(ii)NaBH / OH
(3) XeF
< XeO
F
< XeO
< XeF
4
4
2
2
3
6
(4) XeF
< XeF
< XeO
F
< XeO
4
6
2
2
3
CH
44. Which can be used for temporary bleaching?
3
|
(1) Cl
(2) O
(1)
CH
-
CH
- -
C CH
2
3
3
2
2
|
|
(3) SO
(4) H
O
OH HgOAC
2
2
2
45. The name of the compound is
CH
3
|
4
5
2 3
(2)
CH
-
CH
- -
C CH
3
2
3
|
1
OH
(1) (2Z, 4Z) –2, 4hexadiene
(2) (2Z, 4E) –2, 4hexadiene
CH
3
|
(3) (2E, 4Z) –2, 4hexadiene
(3)
CH
-
CH
-
CH CH
-
3
2
2
(4) (2E, 4E) –2, 4hexadiene
|
OH
46. R–alanine is represented by
CH
3
COOH
NH
|
2
(4)
CH
- -
C CH
-
OH
3
2
|
NH
H
(1)
H
(2)
H C
2
3
CH
3
CH
COOH
3
50. Identify ‘B’
NH
COOH
Br / CCl
2
4
2
C H
-
CH
=
CH
¾¾¾¾¾ ®
[A]
6
5
2
HOOC
CH
CH
NH
(3)
(4)
(
)
3
3
2
(i) NaNH
3.0 equivalent
2
¾¾¾¾¾¾¾¾¾¾ ®
[B]
(ii) CH
-
I
3
H
H
(1) C
H
–CH = CH
6
5
2
47. Which one of the following is most acidic in nature ?
(2) C
H
–C º CH
6
5
(1) CH
COOH
3
(3) C
H
–C º C–CH
6
5
3
(2) HOCH
—COOH
2
C H
-
C CH CH
=
-
(4)
(3) NC—CH
—COOH
6 5
3
2
|
(4) NO
—CH
—COOH
CH
2
2
3
Space Fo r Ro ugh Wo rk