Reference: Mole Calculations & Percent Compositions Page 2

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Pre-AP Chemistry
Use empirical formula to find the percent composition.
Percent Composition
1. Use the formula subscript and the mass of one mole to
get the total grams of each element present in the
There are two main types of these problems.
compound.
2. Find the total mass of one mole of the compound.
1. Use the percent composition to find the empirical
3. Divide each individual element mass by the total mole
formula.
mass.
2. Use the empirical formula to find the percent
composition.
Example: Find the percent composition of each element
in carbon dioxide.
à
3. Use a percent composition to find how much of a single
1. CO
2
element is present.
C=12 grams present
2 × O = 2(16) = 32 grams present.
Most problems that you will see in here are variations of
working in these two directions.
2. CO
= 12 + 2(16) = 44 grams total for one mole
2
Use Percent Composition to find formula.
3. 12 grams ÷ 44 = 0.273 = 27.3%
32 ÷ 44 = 0.727 = 72.7%
1. Pretend that you have 100 grams of the substance. The
percentages become the mass of each.
Example: Find the percent of oxygen in BaCO
. How
3
2. Change the gram amounts of each element into moles
much oxygen would be in 22.8 grams of BaCO
?
3 ?
3. Divide all the moles of each by the smallest of the mole
1. Ba=137.33 grams,
answers to get a relative amount.
C=12.0 grams
3 × O = 3(16) = 48 grams present
4. Sometimes you have to double or triple (or multiple by
some other factor) to get the values to all be whole numbers.
2. CaCO
=40.1+12.0+48 = 197.3 grams for one mole
3
Example: A compound is 27% carbon and 73% oxygen.
3. 48 grams ÷197.3 = 0.243 = 24.3%
Determine the empirical formula
4. 22.8 grams of compound × 0.243 = 5.55 grams
1. 27 grams of carbon, 73 grams of oxygen.
2. 1 mole
× 27 grams = 2.25 moles of carbon
12.0g
1mole
×73 grams = 4.5625 moles of oxygen
16.0g
3. 2.25 ÷ 2.25 = 1.00
4. 4.5625÷2.25 = 2.03
These two answers round to whole numbers: 1 C to 2 O =
CO
2
Handout: Mole Calculations
2
11/20/14

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