Additional Science - Chemistry Checklist Page 2

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released from forming new bonds
Catalysts provide a different pathway for a chemical reaction that has a lower activation energy
Hydrogen can be burned as a fuel in combustion engines. It can also be used in fuel cells that produce
electricity to power vehicles. Hydrogen + Oxygen $ Water
Flame tests identify metal ions. lithium $ crimson, sodium compounds $ yellow, potassium compounds $
lilac, calcium compounds $ red, barium compounds$ green
Aluminium, calcium & magnesium ions form white precipitates with sodium hydroxide solution but only the
aluminium hydroxide precipitate dissolves in excess sodium hydroxide solution
Copper(II), iron(II) & iron(III) ions form coloured precipitates with sodium hydroxide solution. Copper forms
a blue precipitate, iron(II) a green precipitate & iron(III) a brown precipitate
Carbonates react with dilute acids to form carbon dioxide. Carbon dioxide produces a white precipitate with
limewater. This turns limewater cloudy
Halide ions in solution produce precipitates with silver nitrate solution in the presence of dilute nitric acid.
Silver chloride is white, silver bromide is cream & silver iodide is yellow
Sulfate ions in solution produce a white precipitate with barium chloride solution in the presence of dilute
hydrochloric acid
The volumes of acid & alkali solutions that react with each other can be measured by titration using a
suitable indicator
HT: If the concentration of one of the reactants is known, the results of a titration can be used to find
the concentration of the other reactant
The raw materials for the Haber process are nitrogen & hydrogen. Nitrogen is obtained from the air &
hydrogen may be obtained from natural gas or other sources
The purified gases are passed over a catalyst of iron at a high temperature & a high pressure Some hydrogen
& nitrogen reacts to form ammonia. The reaction is reversible. Remaining hydrogen & nitrogen are recycled
HT: When a reversible reaction occurs in a closed system, equilibrium is reached when the reactions
occur at exactly the same rate in each direction. Relative amounts of reacting substances at
equilibrium depend on the conditions of the reaction
HT: If the temperature is raised, the yield from the endothermic reaction increases & the yield from the
exothermic reaction decreases
HT: If the temperature is lowered, the yield from the endothermic reaction decreases & the yield from
the exothermic reaction increases
HT: In gaseous reactions, an increase in pressure will favour the reaction that produces the least
number of molecules as shown by the symbol equation for that reaction
HT: These factors, together with reaction rates are important when determining the optimum
conditions in industrial processes, including the Haber process
Alcohols contain the functional group –OH. Methanol, ethanol & propanol are the first three members of a
homologous series of alcohols
Methanol, ethanol & propanol dissolve in water to form a neutral solution, react with sodium to produce
hydrogen, burn in air, are used as a fuels & solvents, & ethanol is the main alcohol in alcoholic drinks
Ethanol can be oxidised to ethanoic acid, either by chemical oxidising agents or by microbial action. Ethanoic
acid is the main acid in vinegar
Ethanoic acid is a member of the carboxylic acids, which have the functional group –COOH
HT: It does not ionise completely when dissolved in water & so is a weak acid. Aqueous solutions of
weak acids have a higher pH value than aqueous solutions of strong acids with the same concentration
Ethyl ethanoate is the ester produced from ethanol & ethanoic acid. Esters have the functional group –
COO–. They are volatile compounds with distinctive smells & are used as flavourings & perfumes
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