2
Ways to get a buffer system:
• Mixing a weak acid and its salt, e.g., HCN and NaCN
• Mixing a weak base and its salt, e.g., NH 3 and NH 4 Cl
• Titration or mixing problems where a weak acid and a strong base are mixed at the point
where there is some weak acid (left) and some of its salt (newly formed) are present.
• Titration or mixing problems where a weak base and a strong acid are mixed at the point
where there is some weak base (left) and some of its salt (newly formed) are present.
Equivalence Point:
When an equivalent amount of an acid and a base are added to each other causing
neutralization.
•
For a strong acid and a strong base, all that is formed is a salt that will not hydrolyze, i.e.,
neither the anion or the cation wants to steal or give an H + .
For a weak acid and strong base, the salt anion (A - ) undergoes hydrolysis (steals some H +
•
from H 2 O) giving a basic solution.
For a weak base and strong acid, the salt anion (BH + ) undergoes hydrolysis (gives up
•
some H + ) giving an acidic solution.