Molecular Orbital Diagrams

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Morning class week 4 day 3: Molecular orbital diagrams
1. An understanding of molecular orbitals, like atomic orbitals starts with sand patterns on drums.
(a) The atomic orbital drum analog: Draw a shelf (energy) diagram which goes with the picture
below. Draw contour maps and balloon diagrams for each wavefunction.
Figure 1: The lowest energy portion of the atomic orbital diagram.
(b) The H
molecular orbital drum analog: Draw a shelf (energy) diagram which goes with the
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picture below. Draw contour maps and balloon diagrams for each wavefunction.
Figure 2: H
molecular orbital diagram.
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+
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(c) The H
molecular orbital drum analog: H
is an interstellar ion in which the three hydrogen
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atoms form a perfect equilateral triangle. Draw a shelf (energy) diagram which goes with the
picture below. Draw contour maps and balloon diagrams for each wavefunction.
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