Solubility Of Selected Gases In Water Page 3
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1
2
3
4Solubility of Selected Gases in Water
8-82
Gas
T/K
Solubility (X
)
Equation constants
Ref.
1
2.46 × 10
298.15
C = 5.6855
–2
2.10 × 10
Std. dev. = ±1.8%
303.15
–2
1.80 × 10
308.15
Temp. range = 278.15—328.15
–2
2.48 × 10
± 2%
Chlorine (Cl
)
283.15
Experimental data
11
–3
2
1.88 × 10
± 2%
M
= 70.9054
293.15
–3
Temp. range = 283.15—333.15
r
1.50 × 10
± 2%
303.15
–3
1.23 × 10
± 2%
313.15
–3
5.25 × 10
± 1%
Chlorine monoxide (Cl
O)
273.15
Experimental data
11
–1
2
4.54 × 10
± 1%
M
= 86.9048
276.61
Temp. range = 273.15—293.15
–1
r
4.273 × 10
± 1%
283.15
–1
3.353 × 10
± 1%
293.15
–1
2.67 × 10
Chlorine dioxide (ClO
)
288.15
A = 7.9163
11
–2
2
2.20 × 10
M
= 67.4515
293.15
B = 0.4791
–2
r
1.823 × 10
298.15
C = 11.0593
–2
1.513 × 10
Std. dev. = ±4.6%
303.15
–2
1.259 × 10
308.15
Temp. range = 283.15—333.15
–2
3.122 × 10
Methane (CH
)
288.15
A = –115.6477
12
–5
4
2.806 × 10
M
= 16.0428
293.15
B = 155.5756
–5
r
2.552 × 10
298.15
C = 65.2553
–5
2.346 × 10
303.15
D = –6.1698
–5
2.180 × 10
Std. dev. = ±0.056%
308.15
–5
Temp. range = 273.15—328.15
4.556 × 10
Ethane (C
H
)
288.15
A = –90.8225
13
–5
2
6
3.907 × 10
M
= 30.0696
293.15
B = 126.9559
–5
r
3.401 × 10
298.15
C = 34.7413
–5
3.002 × 10
Std. dev. = ±0.13%
303.15
–5
2.686 × 10
308.15
Temp. range = 273.15—323.15
–5
3.813 × 10
Propane (C
H
)
288.15
–5
A = –102.044
14
3
8
3.200 × 10
M
= 44.097
293.15
B = 144.345
–5
r
2.732 × 10
298.15
C = 39.4740
–5
2.370 × 10
Std. dev. = ±0.012%
303.15
–5
2.088 × 10
308.15
Temp. range = 273.15—347.15
–5
3.274 × 10
Butane (C
H
)
288.15
A = –102.029
14
–5
4
10
2.687 × 10
M
= 58.123
293.15
–5
B = 146.040
r
2.244 × 10
298.15
C = 38.7599
–5
1.906 × 10
Std. dev. = ±0.026%
303.15
–5
1.645 × 10
308.15
Temp. range = 273.15—349.15
–5
2.333 × 10
2-Methyl propane (Isobutane)
288.15
A = –129.714
14
–5
1.947 × 10
(C
H
)
293.15
B = 183.044
–5
4
10
1.659 × 10
M
= 58.123
298.15
C = 53.4651
–5
r
1.443 × 10
Std. dev. = ±0.034%
303.15
–5
1.278 × 10
308.15
Temp. range = 278.15—318.15
–5
References
5. R. Battino, Ed., IUPAC Solubility Data Series, Vol. 7, Oxygen and
Ozone, Pergamon Press, Oxford, England, 1981.
6. R. Battino, Ed., IUPAC Solubility Data Series, Vol. 10, Nitrogen and
1. C. L. Young, Ed., IUPAC Solubility Data Series, Vol. 5/6, Hydrogen
Air, Pergamon Press, Oxford, England, 1982.
and Deuterium, Pergamon Press, Oxford, England, 1981.
7. C. L. Young, Ed., IUPAC Solubility Data Series, Vol. 8, Oxides of
2. H. L. Clever, Ed., IUPAC Solubility Data Series, Vol. 1, Helium and
Nitrogen, Pergamon Press, Oxford, England, 1981.
Neon, Pergamon Press, Oxford, England, 1979.
8. R. W. Cargill, Ed., IUPAC Solubility Data Series, Vol. 43, Carbon
3. H. L. Clever, Ed., IUPAC Solubility Data Series, Vol. 4, Argon,
Monoxide, Pergamon Press, Oxford, England, 1990.
Pergamon Press, Oxford, England, 1980.
9. R. Crovetto, Evaluation of Solubility Data for the System CO2-H2O, J.
4. H. L. Clever, Ed., IUPAC Solubility Data Series, Vol. 2, Krypton, Xenon
Phys. Chem. Ref. Data, 20, 575, 1991.
and Radon, Pergamon Press, Oxford, England, 1979.
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