Chapter 5: Thermodynamics Worksheet With Answers - Ap Chemistry 2015-2016 Page 11

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7.   What   i s   t he   Δ E   f or   a   s ystem   w hich   h as   t he   f ollowing   t wo   s teps:  
 
Step   1 :   T he   s ystem   a bsorbs   6 0   J   o f   h eat   w hile   4 0   J   o f   w ork   a re   p erformed   o n   i t.  
 
Step   2 :   T he   s ystem   r eleases   3 0   J   o f   h eat   w hile   d oing   7 0   J   o f   w ork.  
 
a)  100   J  
c)   30   J  
 
b)   9 0   J  
d)   zero  
 
8.   When   t wo   s olutions   r eact   t he   c ontainer   “ feels   h ot.”     T hus,  
 
a)  the   r eaction   i s   e ndothermic.  
 
b)   t he   r eaction   i s   e xothermic.  
 
c)   the   e nergy   o f   t he   u niverse   i s   i ncreased.  
 
d)   t he   e nergy   o f   b oth   t he   s ystem   a nd   t he   s urroundings   i s   d ecreased.  
 
9.   The   e quation   f or   t he   s tandard   e nthalpy   o f   f ormation   o f   N
O
  i s  
2
3
 
a)  N
O(g)   +   O
(g)   →   N
O
(g)  
2
2
2
3
 
b)   N
O
(g)   →   N
O
(g)   +   O
(g)  
2
5
2
3
2
 
c)   NO(g)   +   N O
(g)   →   N
O
(g)  
2
2
3
 
d)   N
(g)   +  
/
  O
(g)   →   N
O
(g)  
3
2
2
2
2
3
 
10.   For   t he   g eneral   r eaction  
 
  2   A   +   B
  →   2   A B,    
ΔH   i s   + 50.0   k J.  
2
 
We   c an   c onclude   t hat  
 
a)   t he   r eaction   i s   e ndothermic.  
 
b)   t he   s urroundings   a bsorb   e nergy.  
 
c)  the   s tandard   e nthalpy   o f   f ormation   o f   A B   i s   -­‐‑ 5 0.0   k J.  
 
d)   t he   m olecule   A B   c ontains   l ess   e nergy   t han   A   o r   B
.  
2
 
11.   Calculate   t he   e nthalpy   o f   c ombustion   o f   C
H
  [ C
H
(g)   +  
/
O
(g)   →   3 CO
  +   3 H
O]   u sing   t he   f ollowing:  
9
3
6
3
6
2
2
2
2
 
3C(s)   +   3 H
(g)   →   C
H
(g)  
ΔH°=   5 3.3   k J  
2
3
6
 
C(s)   +   O
(g)   →   C O
(g)    
ΔH°=-­‐‑ 3 94   k J  
2
2
 
H
(g)   +  
/
O
(g)   →   H
O(l)  
ΔH°=-­‐‑ 2 86   k J  
1
2
2
2
2
 
a)  -­‐‑ 1 517   k J  
c)   -­‐‑ 6 26   k J  
 
b)   1 304   k J  
d)   -­‐‑ 2 093   k J  
 
12.   Which   o ne   o f   t he   f ollowing   w ould   h ave   a n   e nthalpy   o f   f ormation   v alue   ( ΔH
)   o f   z ero?  
f
 
a)  H
O(g)  
c)   H
O(l)  
2
2
 
b)   O (g)  
d)   O
(g)  
2
 
13.  
Calculate   t he   h eat   o f   v aporization   o f   t itanium   ( IV)   c hloride:     T iCl
(l)   →   T iCl
(g)   u sing   t he   f ollowing  
4
4
enthalpies   o f   r eaction:  
 
Ti(s)   +   2 Cl
(g)   →   T iCl
(l)  
ΔH°=-­‐‑ 8 04.2   k J  
2
4
 
TiCl
(g)   →   2 Cl
(g)   +   T i(s)   ΔH°=   7 63.2   k J  
4
2
 
a)  -­‐‑ 1 567   k J  
c)   1165   k J  
 
b)   -­‐‑ 7 83.7   k J  
d)   41   k J  
 
 
 
 
 
 

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