Chapter 5: Thermodynamics Worksheet With Answers - Ap Chemistry 2015-2016 Page 6

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8.   Somewhat   C onfusing   D efinitions:  
There   a re   s everal   t erms   u sed   i n   t his   c hapter   t hat   s ound   v ery   s imilar.     U se   t he   d ata   p rovided   t o  
calculate   e ach   o f   t hem   t o   c larify   t he   d ifferences.     I ’ve   a dded   s ome   “ Notes”   t hat   I   h ope   w ill   h elp.  
 
74.8   J   o f   h eat   i s   r equired   t o   r aise   t he   t emperature   o f   1 8.69   g   o f   s ilver   f rom   1 0.0 ° C   t o   2 7.0 ° C.  
 
a.   What   i s   t he   h eat   c apacity   o f   t he   s ilver   s ample?   ( J/°C)  
  Note:     T his   i s   a   u seful   v alue   o nly   f or   t his   s pecific   s ample   o f   s ilver.  
4.4   J /˚C  
 
 
 
b.   What   i s   t he   s pecific   h eat   c apacity   o f   s ilver?   ( J/g·°C)  
 
  Note:     T his   i s   a   u seful   v alue   f or   a ny   s ample   o f   s ilver   t hat   i s   h eated   o r   c ooled.     T his   i s   e quivalent   t o  
the   4 .184   J ·g
·°C
  t hat   w e   u se   f or   w ater.     T his   v alue   i s   a lso   c alled   t he   s pecific   h eat.  
-­‐‑ 1
-­‐‑ 1
0.235   J /g*˚C  
 
5.6-­‐‑ 5 .7:   H ess’s   L aw   a nd   E nthalpies   o f   F ormation  
Use   s tandard   e nthalpies   o f   f ormation   ( appendix   C )   t o   d etermine   t he   c hange   i n   e nthalpy   f or   e ach  
reaction  
a)   N aOH(s)   +   H Cl(g)   -­‐‑ -­‐‑ -­‐‑ -­‐‑ >   N aCl(s)   +   H
O(g)  
2
-­‐‑ 1 33.9   k J  
 
 
 
b)   2   C O(g)   +   O
(g)   -­‐‑ -­‐‑ -­‐‑ >   2   C O
(g)    
2
2
-­‐‑ 5 66   k J  
 
 
 
c)   CH
(g)   +   2   O
(g)   -­‐‑ -­‐‑ -­‐‑ >   C O
(g)   +   2   H
O(l)    
4
2
2
2
-­‐‑ 8 90.3   k J  
 
 
 
d)   2   H
S(g)   +   3   O
(g)   -­‐‑ -­‐‑ -­‐‑ >   2   H
O(l)   +   2   S O
(g)    
2
2
2
2
-­‐‑ 1 123.6   k J  
 
 
 
e)       2   N O(g)   +   O
(g)   -­‐‑ -­‐‑ -­‐‑ >   2   N O
(g)    
2
2
-­‐‑ 1 13   k J  
 
 
 
1.   Using   s tandard   e nthalpies   o f   f ormation,   c alculate   t he   s tandard   e nthalpy   c hange   f or   t he   c ombustion   o f  
1   m ol   b enzene,   C
H
(l),   t o   C O
  ( g)   a nd   H
O   ( l).      
6
6
2
2
-­‐‑ 3 267.4   k J  
 
 
 
 
 

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