Chapter 5: Thermodynamics Worksheet With Answers - Ap Chemistry 2015-2016 Page 14

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10.  
When   a mmonia   i s   o xidized   t o   n itrogen   d ioxide   a nd   w ater,   t he   q uantity   o f   h eat   r eleased   e quals   3 49  
kJ   p er   m ol   o f   a mmonia:  
2NH
(g)     +    
/
O
(g)     →       2 NO
(g)     +     3 H
O(l)  
ΔH°   =   -­‐‑ 6 98   k J  
7
3
2
2
2
2
Calculate   t he   s tandard   m olar   e nthalpy   o f   f ormation   o f   a mmonia   i f  
  ( H
O(l))   =   -­‐‑ 2 86   k J/mol  
ΔH°
f
2
  ( NO
(g))   =   + 33   k J/mol  
ΔH°
f
2
 
 
-­‐‑ 4 7   k J/mol  
 
 
 
 
 
 
11.  
When   4 0   g rams   o f   a mmonium   n itrate   i s   d issolved   i n   1 00   g rams   o f   w ater   i n   a   c onstant-­‐‑ p ressure  
coffee-­‐‑ c up   c alorimeter,   t he   t emperature   o f   t he   s olution   d rops   b y   2 2.4°C.     I f   t he   s pecific   h eat   o f   t he  
solution   i s   4 .18   J K
g
,   c alculate   t he   e nthalpy   o f   s olution   o f   a mmonium   n itrate.  
-­‐‑ 1
-­‐‑ 1
 
 
26.2   k J/mol  
 
 

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