Chapter 5: Thermodynamics Worksheet With Answers - Ap Chemistry 2015-2016 Page 7

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2.   Using   s tandard   e nthalpies   o f   f ormation,   c alculate   t he   e nthalpy   c hange   f or   t he   c ombustion   o f   1   m ol   o f  
ethanol:   C
H
OH   ( l)     +     3 O
  ( g)     →   2 CO
  ( g)     +     3 H
O   ( l)  
2
5
2
2
2
-­‐‑ 1 366.7   k J  
 
 
 
 
 
3.   The   s tandard   e nthalpy   c hange   f or   t he   r eaction   C aCO
(s)   →   C aO(s)     +     C O
(g)   i s   1 78.1   k J.     F rom   t he  
3
2
values   f or   t he   s tandard   e nthalpy   o f   f ormation   o f   C aO(s)   a nd   C O
(g),   c alculate   t he   s tandard   e nthalpy   o f  
2
formation   o f   C aCO
(s).  
3
-­‐‑ 1 207.1   k J  
 
 
 
 
 
 
4.   Given   t he   f ollowing   s tandard   e nthalpy   o f   r eaction,   u se   t he   s tandard   e nthalpies   o f   f ormation   t o  
calculate   t he   s tandard   e nthalpy   o f   f ormation   o f   C uO(s):  
CuO(s)     +     H
(g)   →   C u(s)     +     H
O(l)                     Δ H°   =   -­‐‑ 1 29.7   k J  
2
2
-­‐‑ 1 56.1   k J  
 
 
 
 
 
 
5.   Using   H ess’s   L aw,   c alculate   t he   s tandard   e nthalpy   o f   f ormation   o f   g aseous   d iborane   ( B
H
)   u sing   t he  
2
6
following   t hermochemical   i nformation:  
 
 
  4B(s)   +   3 O
(g)   →   2 B
O
(s)            
 
 
ΔH   =   -­‐‑ 2 509.1   k J  
2
2
3
 
  2H
(g)   +   O
(g)   →     2 H
O(l)              
 
 
ΔH   =   -­‐‑ 5 71.7   k J  
2
2
2
 
  B
H
(g)   +   3 O
(g)   →   B
O
(s)   +   3 H
O(l)    
 
ΔH   =   -­‐‑ 2 147.5   k J  
2
6
2
2
3
2
 
35.4   k J  
 
 
 
 
 
 
6.   Naphthalene   ( C
H
)   i s   a   s olid   a romatic   c ompound   o ften   s old   a s   m othballs.     T he   c omplete  
10
8
combustion   o f   t his   s ubstance   t o   y ield   C O
(g)   a nd   H
O(l)   a t   2 5°   C   y ields   5 154   k J/mol.  
2
2
a)   W rite   b alanced   e quations   f or   t he   f ormation   o f   n aphthalene   f rom   t he   e lements   a nd   f or   i ts   c ombustion.  
 
  b)   C alculate   t he   s tandard   e nthalpy   o f   f ormation   o f   n aphthalene.  
C
H
  ( s)   +   1 2O
  ( g)   →   1 0CO
  ( g)   +   4 H
O   ( l)  
10
8
2
2
2
72.8   k J  
 
 
 

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