4.
Calculate
t he
a mount
o f
h eat
n eeded
t o
m elt
2 7.0
g
o f
i ce
i f
t he
h eat
o f
f usion
o f
i ce
i s
6 .009
k J/mol.
9.003
k J
5.
If
2 7.0
g rams
o f
i ce
a t
0 °C
i s
a dded
t o
1 23
g rams
o f
w ater
a t
1 00°C
i n
a n
i nsulated
c ontainer,
calculate
t he
f inal
t emperature.
A ssume
t hat
t he
s pecific
h eat
o f
w ater
i s
4 .184
J K
g
.
-‐‑ 1
-‐‑ 1
67.7˚C
6.
A
5 0
g ram
b lock
o f
a n
u nknown
m etal
a lloy
a t
1 00°C
i s
d ropped
i nto
a n
i nsulated
f lask
c ontaining
approximately
2 00
g rams
o f
i ce.
I t
w as
d etermined
t hat
1 0.5
g rams
o f
t he
i ce
m elted.
W hat
i s
t he
specific
h eat
c apacity
o f
t he
u nknown
a lloy?
0.70
J /g*K
7.
If
t he
e nthalpy
c hange
f or
t he
c ombustion
o f
p ropane
i s
– 2220
k J/mole
p ropane,
w hat
q uantity
o f
heat
i s
r eleased
w hen
1
k g
o f
p ropane
i s
b urned?
C
H
(g)
+
5 O
(g)
→
3 CO
(g)
+
4 H
O(l)
ΔH-‐‑ 2 220
k J
3
8
2
2
2
-‐‑ 5 0328
k J
8.
Using
t he
f ollowing
t hermochemical
d ata,
c alculate
t he
m olar
h eat
o f
c ombustion,
Δ H°
o f
combustion
methane,
C H
:
4
2CH
(g)
+
3 O
(g)
→
2 CO(g)
+
4 H
O(l)
ΔH°
=
-‐‑ 1 215
k J
4
2
2
2C(s)
+
O
(g)
→
2 CO(g)
ΔH°
=
-‐‑ 2 21
k J
2
C(s)
+
O
(g)
→
C O
(g)
ΔH°
=
-‐‑ 3 94
k J
2
2
-‐‑ 8 91
k J/mol
9.
Calculate
t he
s tandard
m olar
e nthalpy
o f
f ormation
o f
m ethane
f rom
t he
d ata
g iven
i n
q uestion
8 ,
your
a nswer
t o
q uestion
8 ,
a nd
t he
f ollowing:
( H
O(l))
=
-‐‑ 2 86
k J/mol
ΔH°
f
2
-‐‑ 7 5
k J/mol